Example 1: Explaining the Chemistry
Question 1
The diagram shows some important conversion processes used in the oil industry.
Describe how kerosene is produced from crude oil in process 1.
Final answer
Kerosene is produced from crude oil by fractional distillation. The crude oil is heated so that it boils/vapourises, and the vapours enter a fractionating column. The column is hotter at the bottom and cooler at the top. As the vapours rise, they cool. Hydrocarbons with different boiling points condense at different levels in the column. Shorter-chain hydrocarbons have lower boiling points and rise higher. Kerosene condenses at its own level in the column, below refinery gases/gasoline and above diesel/fuel oil.
Mark scheme points
Any five of these points gain full marks.
- M1 States that the process is fractional distillation.
- M2 Says the crude oil is heated or vapourised/boiled.
- M3 Refers to a fractionating column or tower.
- M4 States that the column is hotter at the bottom than at the top.
- M5 Explains that shorter hydrocarbons have lower boiling points and rise higher up the column.
- M6 Says that the vapours/fractions condense at different levels depending on their boiling points, so kerosene condenses at its level.
Explanation
To secure full marks, describe separation, not a chemical reaction.
- Start by naming the process: crude oil is separated by fractional distillation.
- Then say crude oil is heated strongly so that it vapourises/boils.
- Mention that the vapours enter a fractionating column.
- State the temperature gradient: hot at the bottom, cooler at the top.
- Explain the trend: shorter-chain hydrocarbons have lower boiling points, so they travel further up before condensing.
- Finish with the key idea that each fraction condenses at the level that matches its boiling point. Kerosene therefore condenses in the middle region of the column, below gasoline/refinery gases and above diesel/fuel oil.
Common mistakes
- Writing only “fractional distillation” without describing heating, the column, and condensation.
- Confusing fractional distillation with cracking. Kerosene is separated from crude oil, not made by breaking molecules.
- Forgetting the temperature gradient: the column must be hotter at the bottom and cooler at the top.
- Not linking condensation to boiling point.
- Examiners reported that most candidates earned only one or two of the first three points, while stronger answers reached four or five marks. So do more than name the process: add heating, the column, the temperature gradient, and how kerosene condenses.